Perfil do Tradutor: Eric_ZHANG (yong_zhang)

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Ph.D. in Chemistry,
Specialize in chemistry, chemical engineering, pharmaceuticals, and oceanography.
Content types: academic articles, technical documents, and patents.

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earth sciences

academic

chemistry

patents

other

Meu Trabalho

Amostra de Tradução Science

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Fonte (English)	Destino (Chinese)
Phytoplankton blooms can be an important source of autochthonous chromophoric dissolved organic matter (CDOM) in surface oceans.	表层海水中有色溶解有机物 (CDOM) 的一个重要自生来源是浮游植物的藻华。
Here we report the first detection and optical characterization of CDOM produced during a Dictyocha fibula bloom occurring in the western central Bohai Sea in mid-summer 2019.	2019年仲夏，我们在渤海中部偏西的海域观测到一次小等刺硅鞭藻的藻华，对于本次藻华释放的 CDOM 及其光学性质，我们首次进行了报导。
The mean CDOM absorption coefficient at 330 nm (aCDOM(330)) in the surface water of the bloom area (3.16 ± 0.48 m-1) was 2.5 times higher than that of the adjacent bloom-absent area (1.26 ± 0.34 m-1).	在藻华区的表层海水中，CDOM 在 330 nm 处的吸光系(aCDOM(330)) 平均值为 3.16 ± 0.48 m-1，该值是在临近的背景区内观测平均值 (1.26 ± 0.34 m-1) 的 2.5 倍。
The aCDOM(330) increased exponentially to a maximum with increasing chlorophyll a and cell abundance of D. fibula, indicating a steady state was reached between production and consumption of CDOM.	吸光系数 aCDOM(330) 随叶绿素 a 和小等刺硅鞭藻细胞丰度的增加而呈指数方式升高，直到升至一个最高值，此时 CDOM 的产生和消耗达到动态平衡。
The biological index (BIX) of the fluorescent DOM (FDOM) showed little variation between bloom and background areas.	荧光 DOM (FDOM) 的生源指数 (BIX) 在藻华区与背景区内都变化甚微。
The combination of these observations points to an extensive production of autochthonous CDOM by D. fibula in the bloom area.	这些观测结果表明，藻华区内的小等刺硅鞭藻释放了大量的自生源 CDOM。
Mass budgeting indicates that the CDOM source from D. fibula (aCDOM(330): 1.98 ± 0.48 m-1) accounted for 63% of the CDOM stock in the bloom area.	根据质量守恒原理计算得出，小等刺硅鞭藻产生的 CDOM (1.98±0.48 m-1)占藻华区 CDOM 总量的 63%。
The spectral slope coefficients over 275–295 nm (S275–295) in the bloom area (range: 0.0228–0.0241 nm-1; mean: 0.0235 nm-1) were substantially lower than those in the bloom-absent area (range: 0.0240–0.0311 nm-1; mean: 0.0271 nm-1), suggesting a high-molecular-weight nature of the D. fibula-derived CDOM.	藻华区 CDOM 在 275 nm-295 nm 波段的光谱斜率（S275–295) 的测量值 (范围：0.0228-0.0241 nm-1；平均值：0.0235 nm-1) 远低于背景区的值 (范围：0.0240-0.0311 nm-1；平均值：0.0271 nm-1)，这表明小等刺硅鞭藻产生的 CDOM 具有较高的分子量。
The freshly produced CDOM contained two humic-like FDOM components and one protein-like FDOM component, and the three FDOM components were depleted in fresh CDOM relative to their counterparts in CDOM within the background area.	新产生的 CDOM 包含三种 FDOM 组分，其中两种属于类腐殖质，一种属于类蛋白质；这三种 FDOM 组分的含量低于其在背景区内 CDOM 中的含量。
Owing to the episodic nature of algal bloom-driven CDOM production, future attention should be paid to accelerated biogeochemical cycles (e.g., spiked oceanic trace gas emission) associated with CDOM photochemistry during algal blooms which can be easily missed for pre-scheduled field surveys.	藻华的爆发是随机的，藻华释放的 CDOM 亦然；而出海调查都是提前规划好的，不一定恰好遇见每一次藻华。

Amostra de Tradução Law/Patents

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Fonte (English)	Destino (Chinese)
The present invention is an improved method for the preparation of 4-fluoro-3-piperidin-4-yl-benzyl)-carbamic acid tert-butyl ester, compound of formula I.	本发明提供了一种改进的方法用于制备(4-氟-3-哌啶-4-基-苄基)-氨基甲酸叔丁酯，即分子式I所示的化合物。
The invention is also directed to the intermediates 5-((tert-Butoxycarbonyl)amino-methyl)-2-fluorobenzeneboronic acid (compound 11), and (4-fluoro-2-pyridin-4-yl-benzyl)-carbamic acid tert-butyl ester (compound 13).	本发明提供了一种三步合成分子式I化合物的方法，这三个步骤包括生成5-((叔丁氧羰基)氨基甲基)-2-氟苯硼酸(化合物11)，化合物11在Suzuki偶联条件下生成(4-氟-2-吡啶-4-基-苄基)-氨基甲酸叔丁酯的反应，以及在氢化条件下对上述产物的选择性加氢生成化合物I。
1. A method for preparing 5-((tert-butoxycarbonyl)aminomethyl)-2-fluorobenzene-boronic acid, comprising boronation of 4-(tert-butoxycarbonyl)aminomethyl)-fluorobenzene with a boronic acid forming agent under boronation conditions, and then quenching the resultant mixture with an aqueous acid to yield 5-((tert-butoxycarbonyl)aminomethyl)-2-fluoro-benzeneboronic acid.	本发明还涉及中间体5-((叔丁氧羰基)氨基甲基)-2-氟苯硼酸(化合物11)和(4-氟-2-吡啶-4-基-苄基)-氨基甲酸叔丁酯(化合物13)。
2. The method of claim 1 wherein the boronation conditions uses a superbase.	1. 一种制备5-((叔丁氧羰基)氨基甲基)-2-氟苯-硼酸的方法，包括在硼化条件下用硼酸形成剂对4-(叔丁氧羰基)氨基甲基)-氟苯进行硼化，然后用酸溶液淬灭反应混合物生成5-((叔丁氧羰基)氨基甲基)-2-氟苯硼酸。
3. The method of claim 2 wherein the superbase is a combination of an organolithium reagent of formula RLi where R is an alkyl or aryl group having 1-12 carbons and a bulky potassium alkoxide such as potassium tert-butoxide or potassium tert-pentoxide and the like.	2. 根据权利要求1所述的方法，其中硼化条件使用超强碱。
4. The method of claim 3 wherein the superbase is a combination of n-butyllithium and potassium tert-butoxide.	3. 根据权利要求2所述的方法，其中超强碱是分子式为RLi的有机锂试剂与大分子的烷氧基钾例如叔丁醇钾或叔戊醇钾等类似物的组合，其中R是具有1-12碳原子的烷基或芳基。
5. The method of claim 1 wherein the boronation conditions uses a boronic acid forming agent which is a trialkyl boronate.	4. 根据权利要求3所述的方法，其中超强碱是正丁基锂和叔丁醇钾的组合物。
6. The method of claim 5 wherein the trialkyl boronate is selected from trimethyl borate, triethyl borate, tripropyl borate, triisopropyl borate, tributylborate and the like.	5. 根据权利要求1所述的方法，其中硼化条件使用的硼酸形成剂为三烷基硼酸盐。
7. The method of claim 6 wherein the trialkyl boronate is triisopropyl borate.	6. 根据权利要求5所述的方法，其中三烷基硼酸盐选自硼酸三甲酯、硼酸三乙酯、硼酸三丙酯、硼酸三异丙酯、硼酸三丁酯等。
8. The method of claim 1 wherein the boronation conditions uses a boronation solvent which is an ether solvent selected from diethyl ether, THF, 2-methyltetrahydrofuran, MTBE, dimethoxyethane and the like.	7. 根据权利要求6所述的方法，其中三烷基硼酸盐是硼酸三异丙酯。
9. The method of claim 8 wherein the ether solvent is THF.	8. 根据权利要求1所述的方法，其中硼化条件使用选自二乙醚、THF、2-甲基四氢呋喃、MTBE、乙二醇二甲醚等醚溶剂的硼化溶剂。
10. The method of claim 1 wherein the boronation conditions uses a boronation reaction temperature from about -100 oC.	9. 根据权利要求8所述的方法，其中醚溶剂是THF。
to about -30 oC.	10. 根据权利要求1所述的方法，其中硼化条件使用的硼化反应温度从约-100oC至约-30oC。
11. The method of claim 10 wherein the boronation reaction temperature is from about -70 to about -45 oC.	11. 根据权利要求10所述的方法，其中硼化反应的温度从约–70 至约 -45 oC.
12. The method of claim 1 wherein the aqueous acid is HCl or H3PO4.	12. 根据权利要求1所述的方法，其中的酸溶液为 HCl or H3PO4。

Minha Experiência

Experiência

6 anos.

Formação

2008 PhD em Unviersity of China
2005 MA/MS em University of Qubec, Canada

Adesões

Science and Technology Translators' Association of the Chinese Academy (Ingressão: 2015)

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